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Ideal Gas Mean Free Path

Estimate the typical molecular travel distance between collisions from temperature, pressure and collision diameter.

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How to use this calculator

  1. Enter the known values in the units shown. Results update as you type.
  2. Where results are editable, change one to solve backwards. Lock a value to hold it fixed.
  3. Use the worked example to check the method. Reset restores the starting fields.

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Formula and method

At 300 K and 1 atm, a 100 pm collision diameter gives about 920.074 nm with the retained coefficient.

λ = kB T/(√2 π d² p).

Worked example

Enter these known values and leave the other values blank.

Molecule kinetic diameter
100 pm
Pressure
1 atm
Temperature
300 K
Mean free path
920 nm

Assumptions and limitations

  • Dilute ideal gas with hard-sphere collisions; diameter is an effective collision diameter.
  • The captured coefficient 1.38064852 × 10⁻²³ J/K is retained as a historical approximation. The modern exact SI value is 1.380649 × 10⁻²³ J/K, a relative difference of about 0.000035%.
  • Temperature is absolute and pressure and diameter must be positive.
  • Enter known quantities and clear the unknown to use available inverse branches. Locks retain supplied values. Consistency messages cover fully visible equations; identities with hidden dependencies may require a manual consistency check. Preset values are illustrative approximations, and unit selectors preserve the underlying quantity.

Common questions

How do I solve for a different quantity?

Clear that quantity and supply enough independent known values. Some outputs are one-way or tied to a selected preset, so they cannot determine every input.

References

The calculation equations, inverse formulas, units, and input rules were imported from this source. Bookify provides the interface and equation solver.

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