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Equal-Degeneracy Thermal Population Ratio

Calculate the state-one to state-two equilibrium population ratio from energies and temperature.

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Calculator inputs

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How to use this calculator

  1. Enter the known values in the units shown. Results update as you type.
  2. Where results are editable, change one to solve backwards. Lock a value to hold it fixed.
  3. Use the worked example to check the method. Reset restores the starting fields.

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Inputs and results stay in this browser tab. Bookify does not upload or store the values you enter.

Formula and method

boltzmann factor = 1.0000. This worked example uses the displayed units and declared assumptions.

boltzmann_factor = one_way((temperature > 0 and abs((second_energy-first_energy)/(1.380649e-23*temperature)) <= 1000) ? exp((second_energy-first_energy)/(1.380649e-23*temperature)) : 0)

Worked example

Enter these known values and leave the other values blank.

E==1==
0.1 eV
E==2==
0.1 eV
Temperature
300 K
Boltzmann factor
1

Assumptions and limitations

  • n1/n2=exp((E2−E1)/(kBT)) assumes equal degeneracies and thermal equilibrium. The supported numerical exponent magnitude is at most 1000. Direct high-precision arithmetic replaces captured floating-point overflow and large-value rounding; this is not a measured population prediction.
  • Clear an unknown to solve a supported inverse; keep known values fixed with locks. Singular or underdetermined inverses may remain incomplete.

Common questions

What assumptions apply?

n1/n2=exp((E2−E1)/(kBT)) assumes equal degeneracies and thermal equilibrium. The supported numerical exponent magnitude is at most 1000. Direct high-precision arithmetic replaces captured floating-point overflow and large-value rounding; this is not a measured population prediction.

Which unknowns can I solve?

Editable controls preserve the supported captured inverse branches. Clear the desired unknown and provide enough independent known quantities; singular or underdetermined inverses may remain incomplete.

References

Translate the captured binary-floating-point helper to direct high-precision population-ratio arithmetic exp((E2−E1)/(kBT)) for equal degeneracies, preserving its one output branch. Avoid its large-result four-significant-figure rounding; impose a finite numerical exponent range ±1000 and positive temperature. Thermodynamic temperature must be positive. The supported numerical exponent magnitude is at most 1000.

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