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Mass-Fraction ppm to Molarity at 1 kg/L

Convert mass-based parts per million or billion to molarity at the fixed solution-density assumption of 1 kg/L.

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How to use this calculator

  1. Enter the known values in the units shown. Results update as you type.
  2. Where results are editable, change one to solve backwards. Lock a value to hold it fixed.
  3. Use the worked example to check the method. Reset restores the starting fields.

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Formula and method

A solution containing 100 ppm by mass, with density 1 g/mL and solute molar mass 50 g/mol, has concentration 0.002 mol/L.

Molarity in mol/L = mass-based ppm × density in g/mL / (1000 × molar mass in g/mol)

Worked example

Enter these known values and leave the other values blank.

Solute mass fraction
100 ppm
Solute molar mass
50 g/mol
Amount concentration
0.002 M

Assumptions and limitations

  • All quantities are positive. Here ppm means milligrams of solute per kilogram of solution; ppb means micrograms per kilogram.
  • This retained mode fixes solution density at 1 g/mL, equal to 1 kg/L. This mode is unsuitable when a different density is required.
  • These mass fractions are different from gas-volume ppm or mole-fraction ppm. A density of 1 g/mL is a fixed assumption here, not a universal property of aqueous solutions.

Common questions

Is ppm always the same as mg/L?

No. Mass-based ppm equals mg/kg. It has the same numerical value as mg/L only when solution density is 1 kg/L.

Can I use this for ppm by gas volume?

No. Gas-volume and mole fractions need a different conversion based on the specified gas state and fraction definition.

References

Bookify uses exact customary mass and volume definitions for density units, replacing rounded factors in the reference.

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